Peer Review Validates Dry Cathode Manufacturing Process
Released
Released
Announcement PDF
ASX ANNOUNCEMENT
2 JULY 2026
Critical Resources Limited – www.criticalresources.com.au
Level 45, 108 St George's Tce, Perth WA 6000
P: +61 (8) 9465 1024 E. info@criticalresources.com.au
ASX:CRR
INDEPENDENT PEER-REVIEWED PUBLICATION
CONFIRMS CRR’S DRY CATHODE MANUFACTURING
TECHNOLOGY
International peer-reviewed publication confirms DSD dry-deposition process — solvent-free,
binder-free, single-step, with coulombic efficiency above 99.5% over 500 cycles (~1,250 hrs)
- International peer-reviewed validation: CRR’s optioned dry supersonic deposition (DSD)
technology has been validated in a peer-reviewed international journal as a solvent and binder-
free cathode manufacturing method.
- Durable published performance: results are the first set of unoptimised DSD trials in coin cell
format on a liquid-electrolyte reference, delivering approximately 154 mAh/g — near LFP’s
theoretical capacity — and held approximately 85% of its capacity over 500 cycles at 1C (~1,250
hrs), with coulombic efficiency above 99.5%.
- The benefits of dry manufacturing: DSD builds the cathode dry, in a single step directly onto the
current collector — no toxic solvents, no polymer binders, and no drying ovens — removing the
costly, energy and capital-intensive stages of conventional slurry electrode manufacturing.
- De-risks the licensable IP, capital-light: Independent peer review of the core process
strengthens CRR’s position and de-risks the technology, widening the licensing and partnering
opportunity.
- Solid-state electrolyte integration next for All Solid-State Battery (ASSB): The work is a proof-of-
concept on a liquid-electrolyte reference. Integrating CRR’s optioned proprietary sulphur-free
Amorphous Solid Electrolyte (ASE) with the DSD process is the next stage toward an all-solid-state
cell; thin-film ASE deposition and full-format pouch-cell cycling are ongoing.
Critical Resources Limited (‘Critical Resources’ or the ‘Company’, ASX:CRR) is pleased to report that peer-
reviewed research validating the dry supersonic deposition (DSD) cathode technology it holds under
exclusive option has been published in the international journal Electrochimica Acta (Rodmyre et al.,
“Formation mechanism of solvent- and binder-free cathode nanostructures produced by supersonically
accelerated lithium iron phosphate ceramic particles”, Electrochimica Acta, Vol. 574, 2026, article 149386).
The publication provides independent, peer-reviewed confirmation of the solvent and binder-free
manufacturing method at the core of the Company’s licensable intellectual property. The DSD process is the
subject of a provisional patent application, over which CRR holds an exclusive option. CRR’s strategy is to
commercialise this technology through licensing rather than by manufacturing cells itself. The underlying work
Critical Resources Limited – www.criticalresources.com.au
Level 45, 108 St George's Tce, Perth WA 6000
P: +61 (8) 9465 1024 E. info@criticalresources.com.au
ASX:CRR
was conducted at the South Dakota School of Mines & Technology (SDM) within the US National Science
Foundation (NSF) supported Centre for Solid-State Electric Power Storage (CEPS).
The evaluation program is led at SDM by Dr Alevtina Smirnova, Director of the Centre for Solid-State Electric
Power Storage and Technical Advisor to Critical Resources. The Centre operates within the US National
Science Foundation (NSF) supported research framework. Dr Smirnova’s research developed the solid-state
battery IP over which the Company holds its exclusive evaluation option (refer ASX:CRR announcements 17
February 2026 and 18 November 2025).
At this stage of its evaluation program, Critical Resources’ strategy would be to license its battery materials
and manufacturing IP, not to become a manufacturer of cells itself. Each step of the Company’s evaluation
program that de-risks the DSD process — including building it into a working full-format cell — widens the
Company’s potential licensing and partnership opportunities.
WHY DRY MANUFACTURING MATTERS
Conventional battery electrodes are made by a wet “slurry” process: the active material is mixed with a
polymer binder and a solvent, coated onto a metal foil, then passed through long, high-temperature drying
ovens to drive the solvent off. That solvent is typically N-methyl-2-pyrrolidone (NMP) — toxic, costly, and
energy-intensive to evaporate and recover — and the polymer binder (commonly PVDF) is electrically
insulating and can block part of the active surface.
Together, the solvent, the binder and the drying step add significant cost, energy and capital to
manufacturing, and carry an environmental burden. DSD removes them entirely: the ceramic cathode
material is accelerated to supersonic speed and deposited dry, directly onto the current collector, in a single
step — no solvent, no binder, no drying oven.
Conventional cathode manufacturing CRR’s DSD cathode process
Active material dispersed in a solvent-based slurry Uses dry cathode powder
Requires toxic chemical solvents Solvent-free process
Requires a polymer binders reducing conductivity No binder required
Coating dried in ovens, with solvent recovery No drying or solvent-recovery step
Separate press (calendering) step to compact the
coating and raise density
During deposition process material is compacted
to high density
Multiple sequential process steps Fewer process steps
Coating applied to flat sheet substrates
Deposition method suited to 3D printing and form-
fitting geometries
During DSD process the cathode material is built from a dry, accelerated particle stream rather than a wet
coating, the method is inherently suited to deposition onto three-dimensional and form-fitting geometries,
unlike continuous flat-sheet processes.
The published study sets out the formation mechanism of the dry-deposited cathode and its electrochemical
performance, and a key finding is the role of a short heat-treatment step. As-deposited, the supersonically
Critical Resources Limited – www.criticalresources.com.au
Level 45, 108 St George's Tce, Perth WA 6000
P: +61 (8) 9465 1024 E. info@criticalresources.com.au
ASX:CRR
deposited LFP is partially amorphous and underperforms, with lithium-ion diffusion roughly two orders of
magnitude lower than the crystalline material. A moderate anneal (around 350°C) restores crystallinity — a
transformation the authors show is reversible — and, importantly, the heat-treated cathode recovers the
electrochemical performance expected of crystalline LFP, indicating that the dry-deposition process does
not permanently degrade the active material.
At low rate (0.1C), the heat-treated cathode delivered approximately 154 mAh/g — close to LFP’s theoretical
capacity of around 170 mAh/g — confirming that near-full capacity is recovered after dry deposition. This
early, unoptimised first set of DSD trials, it also held approximately 85% of its capacity over 500 cycles
(approximately 1,250 hrs) at 1C, with coulombic efficiency above 99.5%.
Rate capability at higher currents is lower, as expected for an unoptimised first-pass cathode, and improving
high-rate performance forms part of the ongoing optimisation work. Published results used a lithium-metal
anode and a standard liquid electrolyte in coin-cell format, with further optimisation of the deposition
parameters as future work.
The independent peer review provides credibility and validates the innovative manufacturing process of
CRR’s solid-state program, strengthening the program’s position in discussions with potential cell and
component-maker licensees.
The published work uses a liquid electrolyte as a reference; the next stage is to integrate the Company’s
proprietary sulphur-free ASE solid electrolyte with the DSD process, working toward a full solid-state cell. That
integration, together with full-format pouch-cell cycling, is ongoing; both involve extended cycle times, and
results will be reported as they are completed and confirmed.
CRR's Amorphous Solid-State Electrolyte (ASE) — distinct from the LLZO reference phase used in the DSD
composite — has been benchmarked at 3.2 mS cm⁻¹ ionic conductivity and 0.27 eV activation energy:
superionic-class conductivity, competitive with sulphide-class performance, without sulphur, and among the
highest reported for the non-sulphide, non-halide amorphous class from a first-pass, unoptimised composition
(refer ASX:CRR announcement 28 May 2026) with ongoing work to integrate into the pouch-cell platform,
replacing the liquid electrolyte baseline.
CRR’s optioned IP portfolio also includes a high-temperature solid-state electrolyte (HTE), covered by US
Patent 10,991,976 and developed with NASA support (the US Government retains certain rights, as is standard
for federally supported inventions). HTE is part of the Company’s licensable IP position and does not form part
of the current pouch-cell work; its planned role is later integration alongside ASE, as shown in the program
table below (refer ASX:CRR announcement 18 November 2025).
Critical Resources Managing Director, Tim Wither, commented: ‘An international peer-review is real
validation of the work being completed at the South Dakota School of Mines and Technology. Peer review
is a high bar, and clearing it helps de-risks the process that sits at the core of our evaluation program — it
is exactly the kind of third-party endorsement that matters when you are talking to potential partners to
move this technology forward.
The benefits of dry, solvent-free manufacturing are well understood in the industry; what this paper does is
demonstrate them, with data, for our process. These are proof-of-concept from a first, unoptimised set of
trials on a liquid-electrolyte reference, not a finished commercial cell, and the strong numbers belong to
the heat-treated cathode. Even so, holding around 85% of capacity over 500 cycles is a genuinely
encouraging durability result at this stage, and it shows the dry process does not degrade the material. This
Critical Resources Limited – www.criticalresources.com.au
Level 45, 108 St George's Tce, Perth WA 6000
P: +61 (8) 9465 1024 E. info@criticalresources.com.au
ASX:CRR
remains early-stage laboratory work, advanced in a disciplined, capital-light way, with outstanding work
from Dr Smirnova and the South Dakota School of Mines team.’
WHERE WE ARE: PROGRAM PROGRESS AT A GLANCE
Program Stage Workstream Status
Electrolyte material benchmarked (ionic conductivity, stability). ASE (electrolyte) ✓ Complete
Single-step composite layer deposited (cathode + electrolyte +
conductor, solvent-free).
DSD (manufacturing) ✓ Complete
Coin cell electrochemical baseline (charge/discharge vs. known
reference).
DSD (manufacturing) ✓ Complete
Full-format pouch cell prototype - electrochemical baseline
(charge/discharge vs. known reference).
DSD + benchmark
electrolyte
Next
Independent testing of DSD pouch cell prototype.
DSD + benchmark
electrolyte
Next
FULL SOLID-STATE CELL: Solid-state ASE and HTE electrolytes integrated
with DSD process.
ASE + DSD Planned
NEXT STEPS
− Complete pouch-cell performance testing: Complete internal electrochemical testing of the full-format
pouch cells now under evaluation — capacity, efficiency and cycle life — to establish a full-format
performance result, with outcomes to follow.
− Optimise and independently validate: Refine the cell and deposition process on internal results, then
submit the optimised baseline cell for independent third-party electrochemical testing to establish a
validated performance baseline.
− Integrate the solid electrolyte: Replace the liquid baseline with CRR's ASE thin-film electrolyte — deposition
is now underway — building towards a full solid-state cell.
− ASE and HTE via DSD: Advance trials depositing the ASE and HTE electrolytes using the dry DSD process —
the manufacturing endpoint that unifies the sulphur-free solid-state electrolyte with the DSD
manufacturing workstream.
These activities represent defined technical gates within CRR’s broader solid-state battery evaluation
strategy, designed to systematically de-risk solvent-free manufacturing pathways while maintaining a
disciplined, capital-light, laboratory-stage evaluation approach. Outcomes will inform prototype
development strategy and downstream partnership, validation or licensing opportunities aligned with
defence, industrial, and high-reliability infrastructure markets.
Critical Resources Limited – www.criticalresources.com.au
Level 45, 108 St George's Tce, Perth WA 6000
P: +61 (8) 9465 1024 E. info@criticalresources.com.au
ASX:CRR
This announcement has been approved for release by the Board of Directors of Critical Resources.
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information please contact us directly at:
E: info@criticalresources.com.au
P: +61 (8) 9465 1024
ABOUT CRITICAL RESOURCES LIMITED
Critical Resources Limited (ASX:CRR) is an Australian mining and technology company focused on the
discovery and development of critical metals and next-generation technologies essential to a sustainable
future. The Company holds a diversified portfolio including the Mavis Lake Lithium Project in Ontario, Canada,
the Halls Peak Base Metals Project in New South Wales, and a growing gold portfolio in New Zealand.
The scientific and technical information in this announcement relating to the DSD cathode technology is drawn from peer-reviewed
research published in Electrochimica Acta (Rodmyre et al., 2026) and fairly represents that published work. Dr Alevtina Smirnova —
Director of the US National Science Foundation–supported Centre for Solid-State Electric Power Storage at the South Dakota School of
Mines & Technology, Technical Advisor to Critical Resources, and a co-author of the publication — has reviewed and approved the
technical information in this announcement and consented to its inclusion in the form and context in which it appears.
FORWARD LOOKING STATEMENTS
This announcement may contain certain forward-looking statements and projections, including statements regarding the Company’s
solid-state battery technology and intellectual property programs, the expected performance, optimisation and development of its
electrolyte and manufacturing workstreams, the potential applications and markets for that technology, and the Company’s plans with
respect to its mineral properties and programs. Forward-looking statements can generally be identified by words such as ‘may’, ‘expect’,
‘intend’, ‘plan’, ‘target’, ‘potential’, ‘anticipate’ and similar expressions. Such forward-looking statements/projections are estimates for
discussion purposes only and should not be relied upon. They are subject to known and unknown risks, uncertainties and assumptions
and may therefore differ materially from results ultimately achieved. The benchmark assessment and laboratory results referred to in this
announcement are early-stage and are not indicative of commercial performance. There can be no assurance that ongoing
optimisation will achieve improved or commercially viable results, that the Company’s battery technology will be successfully developed,
scaled or commercialised, or that any intellectual property option held by the Company will be exercised or prove valuable. There can
also be no assurance that CRR’s plans for development of its mineral properties will proceed as currently expected, that the Company
will be able to confirm the presence of additional mineral resources, that any mineralisation will prove to be economic, or that a mine
will successfully be developed on any of CRR’s mineral properties. Critical Resources Limited does not make any representations and
provides no warranties concerning the accuracy of the projections and disclaims any obligation to update or revise any forward-looking
statements/projections based on new information, future events or otherwise, except to the extent required by applicable laws. While
the information contained in this announcement has been prepared in good faith, neither Critical Resources Limited nor any of its
directors, officers, agents, employees or advisors give any representation or warranty, express or implied, as to the fairness, accuracy,
completeness or correctness of the information, opinions and conclusions contained in this announcement.
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