Solid-State Electrolyte Rivals Sulphide-Class at Room Temp
Released
Released
Announcement PDF
ASX ANNOUNCEMENT
28 MAY 2026
ASX: CRR
Critical Resources Limited – www.criticalresources.com.au
Level 50, 108 St George's Tce, Perth WA 6000
P: +61 (8) 9465 1024 E. info@criticalresources.com.au
ASX:CRR
SULPHUR-FREE SOLID-STATE ELECTROLYTE BENCHMARKS
SULPHIDE-CLASS PERFORMANCE AT ROOM TEMPERATURE
Peer-reviewed benchmarking shows CRR's first-pass amorphous electrolyte (ASE) benchmarks at superionic-class
ionic conductivity and competitive sulphide-class activation energy — without sulphur, removing the processing
constraint recognised as the principal barrier to scaling solid-state lithium-ion batteries.
- ASE room-temperature ionic conductivity of 3.2 mS cm⁻¹ — benchmarked against published
non-sulphide, non-halide amorphous electrolytes for lithium-ion batteries — is competitive with
sulphide-class benchmark values, without the toxic sulphur risk.
- Solid-state battery advantage: Solid-state battery designs can deliver higher energy density
(more runtime and range at lower weight), improved safety (no flammable liquid electrolyte),
and stable operation across a wider temperature range — critical for defence, aerospace
(drones) and high-density computing applications.
- ASE activation energy competitive with sulphide-class performance: At 0.27 eV, Critical
Resources’ solid-state electrolyte is competitive with sulphide-class chemistry and shows limited
temperature dependence — critical for defence, high-density computing and industrial systems
where conventional lithium-ion faces thermal runaway risk and cooling constraints.
- The real advantage is manufacturability, not just safety: Sulphur-based solid-state electrolytes
are fast — but toxic and costly to manufacture. CRR's results show that performance is
achievable sulphur-free, opening a cleaner and potentially cheaper manufacturing pathway.
- Integrated program approach reinforced: The ASE benchmarking results complement the
Company's Dry Supersonic Deposition (DSD) manufacturing program, reinforcing an integrated
strategy designed to reduce both materials and manufacturing risk during the evaluation
phase.
- Strategic positioning across the battery theme: Critical Resources holds interests in both lithium
resources (Mavis Lake Lithium Project) and next-generation battery technology IP —
advancing independently, but together broadening the Company's optionality across future
partnerships, licensing and commercial pathways.
Critical Resources Limited (‘Critical Resources’ or the ‘Company’, ASX: CRR) is pleased to provide the
following benchmark assessment of its non-sulphide Amorphous Solid-State Electrolyte (ASE) initial results
against published solid-state electrolyte performance data from peer-reviewed scientific literature.
Reference values are derived from peer-reviewed scientific literature (Appendix A).
The Company's ASE program, conducted at the South Dakota School of Mines & Technology (SDM) within
the American National Science Foundation (NSF) supported Centre for Solid State Electric Power Storage
Critical Resources Limited – www.criticalresources.com.au
Level 50, 108 St George's Tce, Perth WA 6000
P: +61 (8) 9465 1024 E. info@criticalresources.com.au
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(CEPS) evaluation framework, reported ionic conductivity of 3.2 mS cm⁻¹ and activation energy of 0.27 eV
from initial testing of its non-sulphide amorphous electrolyte composition (see ASX:CRR announcement 18
March 2026). The reported values were measured by Electrochemical Impedance Spectroscopy (EIS) on
cold-pressed electrolyte pellets at SDM within the NSF-supported CEPS framework, and are benchmarked
against published, peer-reviewed scientific literature — providing an externally-referenced basis for the
comparisons that follow.
Ionic conductivity and activation energy metrics are the primary quantitative indicators of solid-state
electrolyte performance in published literature and are the standard basis for comparing electrolyte classes
across the field. The results demonstrate that CRR’s amorphous solid-state electrolyte (ASE), being developed
by SDM, delivers room-temperature ionic conductivity and activation energy competitive with sulphide-class
materials — without sulphide chemistry.
In plain terms: CRR’s electrolyte moves lithium ions as fast as the leading high-performance materials, but
contains no sulphur. That matters because, until now, this level of transport has come only from sulphide
materials that react with air and must be manufactured under inert atmosphere — widely regarded as the
single biggest obstacle to making solid-state batteries affordably and at scale. Removing sulphur also
removes the toxic-gas failure mode that makes those materials difficult to deploy in the defence, aerospace
and data centre environments. Achieving competitive transport without sulphur, on a first-pass composition,
is the necessary first step in the evaluation program toward a more manufacturable solid-state battery.
Importantly, the ASE program forms a core component of CRR’s integrated battery strategy. It complements
the Company’s Dry Supersonic Deposition (DSD) solvent-free manufacturing evaluation program, with both
workstreams designed to systematically reduce materials and manufacturing risk while maintaining a
disciplined, capital-light laboratory-stage evaluation approach.
BENCHMARKING CONTEXT
In solid-state battery research, ionic conductivity and activation energy are the universal quantitative metrics
used to characterise and compare electrolyte materials:
– Ionic conductivity (mS cm⁻¹): Measures the rate at which lithium ions can move through the electrolyte
at a given temperature. Higher values indicate faster ion transport and are directly linked to battery
charge/discharge rate capability. Values above ~1 mS cm⁻¹ at room temperature are widely cited as
a threshold for practical solid-state battery operation (Figure 1).
– Activation energy (eV): Measures the energy barrier to lithium-ion transport. Lower values indicate that
ion transport is less dependent on temperature — a critical requirement for operation across a broad
temperature range, including low-temperature and extreme environment conditions. Values below
~0.30 eV are considered indicative of super-ionic transport behaviour (Figure 2).
Both metrics must be considered together. High ionic conductivity with high activation energy indicates
performance that degrades significantly at low temperature. Low activation energy with low ionic
conductivity indicates efficient but slow ion transport. CRR's first-pass results achieve both simultaneously and
at room temperature, widening potential applications.
The initial ASE results are compared against published reference values for the principal solid-state electrolyte
classes. All reference values are derived from peer-reviewed scientific literature (Appendix A).
Critical Resources Limited – www.criticalresources.com.au
Level 50, 108 St George's Tce, Perth WA 6000
P: +61 (8) 9465 1024 E. info@criticalresources.com.au
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IONIC CONDUCTIVITY PERFORMANCE
At 3.2 mS cm⁻¹, the ASE electrolyte is shown to be competitive against non-sulphide amorphous electrolytes
at room temperature. It exceeds the two principal oxide benchmarks — LLZO (lithium lanthanum zirconium
oxide, a garnet-type ceramic) at ~0.3 mS cm⁻¹ and NASICON (sodium superionic conductor-type, a
phosphate-based ceramic) at ~0.7 mS cm⁻¹ — by approximately 10x and 4.5x, respectively.
Both LLZO and NASICON oxide electrolytes are recognised for their chemical stability and safety profile but
are constrained by low room-temperature conductivity. CRR's ASE result is also competitive with the widely-
cited sulphide-based electrolyte benchmark reference (~1–2 mS cm⁻¹) — without hydrogen sulphide (H₂S)
gas generation risk.
The result clears the broadly cited ~1 mS cm⁻¹ threshold for practical solid-state operation — more than three
times that level — and this is from an unoptimised first-pass composition. Formulation optimisation is a defined
next step and is expected to improve this figure further.
Figure 1 – Ionic conductivity comparison. Initial ASE results exceed the ~1 mS cm⁻¹ practical operation threshold without sulphide
chemistry — with further improvement expected through ongoing formulation work. HTE = High Temperature Electrolyte
ACTIVATION ENERGY COMPETITIVE WITH SULPHIDE CLASS CHEMISTRY
At 0.27 eV, CRR’s amorphous ASE matches the activation energy of sulphide electrolytes and is competitive
with LGPS (~0.22 eV), the highest-performing sulphide class. It significantly outperforms both oxide benchmarks
(LLZO and NASICON, both ~0.35 eV) and polymer (PEO, ~0.50 eV) (Figure 2).
Critical Resources Limited – www.criticalresources.com.au
Level 50, 108 St George's Tce, Perth WA 6000
P: +61 (8) 9465 1024 E. info@criticalresources.com.au
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Achieving 0.27 eV on a non-sulphide composition is the key result: the field has historically considered
sulphide-class activation energy to be inaccessible without sulphide chemistry. CRR’s first-pass data
challenges that assumption, and is a result of years of combined research by the SDM team.
This has direct relevance to CRR’s strategic positioning in high-temperature and extreme environment
applications, where broad temperature range operation is a primary technical requirement. Data centres,
defence installations, and industrial energy storage systems demand batteries that maintain high ionic
conductivity and superior energy density across sustained thermal loads — operating environments where
conventional lithium-ion batteries face accelerated degradation, thermal runaway risk, and performance
constraints. Low activation energy is the fundamental materials property that enables reliable solid-state
battery operation under these demanding conditions.
Figure 2 - Activation Energy comparison. CRR's amorphous ASE achieves activation energy the field has historically associated
only with sulphide-class electrolytes - directly relevant to broad-temperature-range applications.
COMBINED PERFORMANCE SIGNIFICANCE
Achieving both high ionic conductivity and low activation energy on a first-pass non-sulphide composition is
the central result of this benchmarking exercise. Published peer-reviewed literature describes a persistent
trade-off between non-sulphide chemistries and sulphide-class transport performance — sulphide-class
transport has come bundled with sulphide processing. CRR's initial ASE results challenge that assumption.
CRR’s first-pass amorphous ASE delivers competitive ionic conductivity compared to non-sulphide, non-halide
amorphous electrolytes and activation energy competitive with sulphide electrolytes — without the
challenges associated with sulphide-based chemistry. Both results are from an unoptimised composition, with
further potential improvements through ongoing work.
Critical Resources Limited – www.criticalresources.com.au
Level 50, 108 St George's Tce, Perth WA 6000
P: +61 (8) 9465 1024 E. info@criticalresources.com.au
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TWO WORKSTREAMS, ONE INTEGRATED STRATEGY
The initial ASE and DSD results are not independent milestones — they are complementary components of a
single integrated strategy. Solid-state battery development requires both: an electrolyte that conducts lithium
ions efficiently across a wide temperature range and manufactured in a way that is compatible with solid-
state architectures.
– ASE program (electrolyte): Addresses the core materials challenge — ionic conductivity and activation
energy. Initial benchmark results establish competitive performance on both primary metrics from a first-
pass, unoptimised composition.
– DSD program (manufacturing): Addresses manufacturing pathway — solvent-free, low-temperature
cathode/electrolyte fabrication. Initial results establish feasibility of the solvent-free approach and a
repeatable manufacturing baseline, with readiness on electrolyte application.
Both workstreams are now generating data toward DSD integration trials — the next step, in which cathode
and electrolyte architectures developed under each program are brought together into unified solid-state
cell configurations. This is the critical bridge between component-level validation and full-cell prototype
development.
The initial ASE results sit at the foundation of a staged cell-development pathway — compression and
densification, coin-cell cycling, then pouch-cell formats — with each stage providing a discrete validation
point. The coin-cell stage is currently in progress at SDM (Figure 3).
Solid-state battery technology also directly addresses one of the most significant infrastructure challenges
facing high-density computing environments. Conventional lithium-ion battery systems generate substantial
heat under load and carry thermal runaway risk, requiring dedicated cooling and containment infrastructure
in data centre deployments. The low activation energy of CRR’s ASE (0.27 eV) — which enables stable lithium-
ion transport across a broad temperature range — is a fundamental materials property that reduces thermal
sensitivity and improves reliability under sustained thermal load. The Company continues to evaluate
complementary technology opportunities in thermal management of battery technology.
Critical Resources Managing Director, Tim Wither, commented: ‘Benchmarking our first-pass ASE results
against published peer-reviewed literature reveals a performance position that is a result of years of
combined research by Dr Smirnova and the SDM team. Being competitive on ionic conductivity — and
matching sulphide-class activation energy — from an initial composition is a strong starting point.
'The industry has generally accepted a trade-off of toxicity and manufacturing challenges between non-
sulphide safety and sulphide-class performance. The initial results from SDM challenge that assumption. We
are not claiming commercial readiness — this is early-stage laboratory validation, but the technical merits
are very encouraging.
'Importantly, our composition optimisation program is just beginning. The next steps in the ASE and DSD
programs are designed to enhance cell performance and prototype readiness further. There is material
upside from where we are today, and we are pursuing it systematically through a low-cost laboratory-
stage evaluation approach.’
Critical Resources Limited – www.criticalresources.com.au
Level 50, 108 St George's Tce, Perth WA 6000
P: +61 (8) 9465 1024 E. info@criticalresources.com.au
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Figure 3 – Critical Resources test cells under evaluation on a 48-channel Arbin coin-cell cycler at the South Dakota School of
Mines & Technology (SDM), which runs cells through repeated charge cycles to validate real-world performance and durability.
MARKET CONTEXT
Solid-state batteries are widely identified as the next major step-change in energy storage, with higher energy
density — more usable energy per unit weight and volume — among the principal advantages driving that
interest. Independent market research estimates the global solid-state battery market at approximately
US$1.1–1.4 billion in 2024–25, growing to around US$22–27 billion by 2034, a compound annual growth rate
above 30% (Appendix A - GM Insights, 2025; Research and Markets, 2025; InsightAce Analytic, 2025). A
recurring theme across that research is that manufacturability and scale-up — rather than fundamental
materials performance — represent the principal near-term commercialisation barrier, the precise constraint
CRR's sulphur-free pathway is positioned to address.
CRR's initial target environments — data centres, defence and high-reliability industrial systems — sit among
the fastest-growing demand pools for advanced energy storage, and are precisely the settings where energy
density and thermal stability are most valued: weight, footprint and cooling load are binding constraints in
each. Global data-centre electricity demand is projected to more than double by 2030 to around 945 TWh
— comparable to Japan's current total electricity consumption — driven primarily by AI ( Appendix A -
International Energy Agency, Energy and AI, 2025). These are third-party market estimates referenced for
context only; they are not forecasts of the Company's revenue or performance and are not adopted by CRR
as guidance.
STRATEGIC ELECTROLYTE POSITIONING: NON-SULPHIDE PATHWAY
Sulphide electrolytes are the most frequently cited near-term solid-state commercialisation candidates, and
for good reason: the soft, polarisable sulphur lattice both delivers fast lithium-ion transport and allows
electrolyte layers to be densified by cold-pressing rather than high-temperature sintering. CRR’s amorphous
ASE achieves ionic conductivity and activation energy competitive with that sulphide-class benchmark —
but with no sulphur in the composition. The significance is not principally one of safety; it is that sulphide-class
performance has, until now, come bundled with sulphide processing.
Critical Resources Limited – www.criticalresources.com.au
Level 50, 108 St George's Tce, Perth WA 6000
P: +61 (8) 9465 1024 E. info@criticalresources.com.au
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Sulphide electrolytes react with atmospheric moisture and must be synthesised, handled and assembled
under inert atmosphere or in ultra-dry rooms — a processing requirement widely identified as the dominant
barrier to producing solid-state batteries at cost and scale. The most visible expression of this is hydrogen
sulphide (H₂S), a toxic gas with an occupational exposure limit of around 1 ppm that sulphides release on
contact with moisture; it is what drives the inert-atmosphere requirement and, in a deployed cell, imposes
containment obligations. The principal non-sulphide alternative — ceramic oxides such as LLZO — avoids air-
reactivity but must be sintered above 1,000°C, which is energy-intensive, produces brittle layers and limits
interfacial contact. The field has therefore faced a persistent trade-off: sulphide-class transport with sulphide
processing, or air-tolerant oxides with low conductivity and difficult fabrication.
CRR’s non-sulphide, non-halide amorphous composition is positioned to sidestep both constraints. The
amorphous (glass-like) structure has no grain boundaries to impede ion transport, conducts uniformly in all
directions, and is inherently more formable than rigid sintered ceramics — properties associated with simpler,
lower-temperature fabrication. The composition also avoids germanium, the costly element in the highest-
conductivity sulphide (LGPS), and the halide elements that constrain competing non-sulphide routes,
consistent with the Company’s critical-minerals positioning. Confirming the processing and interfacial stability
required to realise these manufacturing advantages is an explicit objective of the evaluation program; the
results reported here establish the necessary precondition — that competitive transport is achievable in this
chemistry at all. For the enclosed, ventilation-constrained environments CRR is targeting — defence,
aerospace and data centre infrastructure — a composition that removes the H₂S failure mode is particularly
well suited.
CRR's technology position addresses both ends of the operating-temperature challenge: the
amorphous ASE program, targeting room-temperature performance optimisation, and the halide
antiperovskite electrolyte IP, targeting elevated-temperature operation where conventional
batteries fail. Both positions are sulphur-free — neither carries the hydrogen sulphide (H₂S) failure
mode that makes sulphide electrolytes difficult to deploy in enclosed, ventilation-limited
environments.
Sulphur-free chemistry is more than a safety attribute — it is what makes the material manufacturable,
and it is manufacturability, more than safety alone, that defines the strategic opportunity. Achieving
sulphide-class transport without sulphide processing is the precondition for a cleaner, potentially
lower-cost fabrication pathway; confirming that pathway in practice remains an explicit objective of
the evaluation program.
Together, these directly address lithium-ion battery performance for extreme-environment, defence,
and high-reliability industrial applications — combining broad-temperature capability and the
energy-density potential of solid-state chemistry with the deployment advantages of sulphur-free
processing and a manufacturing pathway positioned for scale.
CRR HALIDE ELECTROLYTES
The crystalline halide electrolyte class is an active area of solid-state battery research. Certain halide
compositions have demonstrated high ionic conductivity in published literature, including values comparable
to CRR's current ASE result. CRR's benchmark claim is appropriately scoped to the non-sulphide amorphous
class — the directly relevant reference for an amorphous composition.
Crystalline halides require inert atmosphere synthesis and handling, are moisture-sensitive under ambient
conditions, and face cathode compatibility and scalable manufacturing challenges that remain active
Critical Resources Limited – www.criticalresources.com.au
Level 50, 108 St George's Tce, Perth WA 6000
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areas of research. These are the constraints that have prevented crystalline halides from progressing to
commercial production despite their conductivity data.
Separately from the ASE program, CRR holds an exclusive option over a lithium halide antiperovskite
electrolyte IP which is a non-sulphide, lithium-halide-based technology that demonstrates performance at
elevated temperatures (50–100°C) — where activation energy decreases and ionic transport improves with
heat. It is a complementary position to the amorphous ASE program, not a competing one.
NOTE ON AMORPHOUS HALIDE ELECTROLYTES
Recent published literature has reported a class of amorphous oxychloride electrolytes (and related
compositions) with ionic conductivities of up to 6.6 mS cm⁻¹ at 25°C (Zhang et al., Nature Communications,
2023 — Appendix A). These materials are amorphous and non-sulphide; CRR’s benchmark claim is therefore
appropriately scoped to the non-sulphide, non-halide amorphous class.
Amorphous oxychloride electrolytes contain chlorine and are halide-containing materials. They share the
core processing constraints of the broader halide class: they are moisture-sensitive under ambient
conditions, require inert atmosphere synthesis and handling, and face the same containment and safety
obligations in deployed systems that make halide chemistry operationally disqualifying in CRR’s target
defence, aerospace, and high-reliability industrial markets. These constraints are generally considered
intrinsic to the halide chemistry itself and remain active areas of research.
CRR’s non-sulphide, non-halide amorphous composition avoids these liabilities entirely. Within that class —
electrolytes containing no sulphur and no halide elements — CRR's 3.2 mS cm⁻¹ result appears to be among
the highest published room-temperature conductivity values identified by the Company.
NEXT STEPS
Critical Resources will continue advancing the ASE program under the structured six-month evaluation
framework with CEPS and SDM, building on these initial results toward later-stage cell-level validation. These
activities are designed to strengthen the technical foundation of the Company’s solid-state battery strategy
without implying commercial manufacturing. These initial benchmark results represent the materials-
validation stage of a defined development pathway. The steps below progress in sequence — from
validated electrolyte performance, through interfacial and densification work, to integrated full-cell
evaluation — with each stage a discrete, measurable milestone toward a representative solid-state cell.
Key next steps include:
• Electrolyte composition optimisation: Refine amorphous electrolyte formulations to further enhance
ionic conductivity, interface stability, and temperature performance — targeting improved
consistency across a broader operating range.
• Expanded interfacial validation: Continue post-cycling electrochemical and XRD/XPS testing across
broader conditions — building the dataset required to model interface behaviour and degradation
over time.
• Compression pathway assessment: Evaluate cell performance under conventional uniaxial pressing
and Warm Isostatic Pressing (WIP) — an emerging densification technique applying uniform pressure
across complex geometries to improve interface contact and reduce resistance to improve
performance and potential scalable manufacturing pathways.
Critical Resources Limited – www.criticalresources.com.au
Level 50, 108 St George's Tce, Perth WA 6000
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• Progressive full-cell evaluation: Integrate optimised electrolyte and cathode formulations into
increasingly representative solid-state cell assemblies — the critical bridge between materials
validation and cell-level performance metrics.
• DSD integration trials: Commence controlled cathode–electrolyte interface trials aligned with DSD-
fabricated cathode architectures — connecting the ASE and DSD workstreams into a unified solid-
state cell evaluation pathway during the evaluation period with SDM.
This announcement has been approved for release by the Board of Directors of Critical Resources.
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ABOUT CRITICAL RESOURCES LIMITED
Critical Resources Limited (ASX:CRR) is an Australian mining and technology company focused on the
discovery and development of critical metals and next generation technologies essential to a sustainable
future. The Company holds a diversified portfolio including the Mavis Lake Lithium Project in Ontario, Canada,
the Halls Peak Base Metals Project in New South Wales, and a growing gold portfolio in New Zealand.
FORWARD LOOKING STATEMENTS
This announcement may contain certain forward-looking statements and projections, including statements regarding the
Company’s solid-state battery technology and intellectual property programs, the expected performance, optimisation
and development of its electrolyte and manufacturing workstreams, the potential applications and markets for that
technology, and the Company’s plans with respect to its mineral properties and programs. Forward-looking statements
can generally be identified by words such as ‘may’, ‘expect’, ‘intend’, ‘plan’, ‘target’, ‘potential’, ‘anticipate’ and similar
expressions. Such forward-looking statements/projections are estimates for discussion purposes only and should not be
relied upon. They are subject to known and unknown risks, uncertainties and assumptions and may therefore differ
materially from results ultimately achieved. The benchmark assessment and laboratory results referred to in this
announcement are early-stage and are not indicative of commercial performance. There can be no assurance that
ongoing optimisation will achieve improved or commercially viable results, that the Company’s battery technology will
be successfully developed, scaled or commercialised, or that any intellectual property option held by the Company will
be exercised or prove valuable. There can also be no assurance that CRR’s plans for development of its mineral properties
will proceed as currently expected, that the Company will be able to confirm the presence of additional mineral
resources, that any mineralisation will prove to be economic, or that a mine will successfully be developed on any of
CRR’s mineral properties. Critical Resources Limited does not make any representations and provides no warranties
concerning the accuracy of the projections and disclaims any obligation to update or revise any forward-looking
statements/projections based on new information, future events or otherwise, except to the extent required by applicable
laws. While the information contained in this announcement has been prepared in good faith, neither Critical Resources
Limited nor any of its directors, officers, agents, employees or advisors give any representation or warranty, express or
implied, as to the fairness, accuracy, completeness or correctness of the information, opinions and conclusions contained
in this announcement.
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APPENDIX A
All benchmark comparisons reference published, peer-reviewed scientific literature. CRR’s results are from
Electrochemical Impedance Spectroscopy (EIS) measurements on cold-pressed electrolyte pellets
conducted at South Dakota Mines within the CEPS framework. These are early-stage laboratory results —
not indicative of commercial performance.
- Li, X. et al. (2023). LaCl₃-based lithium superionic conductor with compatible interface. Nature, 616,
77–83. (Best-in-class crystalline halide: 3.02 mS cm⁻¹, 0.197 eV — included for full and transparent
representation of the halide class.)
- Zhang, S. et al. (2023). A family of oxychloride amorphous solid electrolytes for long-cycling all-solid-
state lithium batteries. Nature Communications, 14, 3780. (Highest-performing published non-sulphide
amorphous electrolyte class: 6.6 mS cm⁻¹ at 25°C. These are halide-containing (oxychloride) materials
requiring inert atmosphere processing — included for full and transparent representation of the
amorphous electrolyte landscape.)
- Janek, J. & Zeier, W.G. (2023). Challenges in speeding up solid-state battery development. Nature
Energy, 8, 230–
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